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Related Concept Videos

Raman Spectroscopy Instrumentation: Overview01:26

Raman Spectroscopy Instrumentation: Overview

A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
Raman Spectroscopy: Overview01:20

Raman Spectroscopy: Overview

The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of photons. When a monochromatic beam of light, typically from a laser source, interacts with a sample, most scattered light has the same frequency as the incident light. This is known as Rayleigh scattering.
However, a small fraction of the scattered light exhibits a frequency shift due to the exchange of energy between the incident photons and the...
IR Absorption Frequency: Hybridization01:21

IR Absorption Frequency: Hybridization

Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that stretch at a...
IR Spectroscopy: Molecular Vibration Overview01:24

IR Spectroscopy: Molecular Vibration Overview

When Infrared (IR) radiation passes through a covalently bonded molecule, the bonds transition from lower to higher vibrational levels. The fundamental vibrational motions that result in infrared absorption can be classified as stretching or bending vibrations.
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
IR Frequency Region: X–H Stretching01:24

IR Frequency Region: X–H Stretching

In IR spectroscopy, signals produced by the X−H bonds (such as C−H, O−H, or N−H) can be observed in the frequency range of  2700–4000 cm–1. The C−H stretching vibration forms sharp bands in the region 2850–3000 cm–1. The presence of the O−H stretching vibration leads to the forming of an absorption band in the frequency range 3650–3200 cm−1. At the same time, N−H stretching can be confirmed by absorption bands in the 3500–3100 cm−1 range. Even though both O−H and N−H bonds vibrate at a similar...
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration01:16

IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration

A covalently bonded heteronuclear diatomic molecule can be modeled as two vibrating masses connected by a spring. The vibrational frequency of the bond can be expressed using an equation derived from Hooke's law, which describes how the force applied to stretch or compress a spring is proportional to the displacement of the spring. In this case, the atoms behave like masses, and the bond acts like a spring.
According to Hooke's law, the vibrational frequency is directly proportional to the...

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Ultrafast Time-resolved Near-IR Stimulated Raman Measurements of Functional &#960;-conjugate Systems
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Published on: February 10, 2020

A cw tunable near-infrared (1.085-1.175-microm) Raman oscillator.

C Lin, R H Stolen, W G French

    Optics Letters
    |August 15, 2009
    PubMed
    Summary
    This summary is machine-generated.

    This study introduces the first continuous-wave (cw) tunable Raman laser operating in the 1.1-micrometer spectrum. Researchers achieved tunable output for first and second Stokes oscillations using a fiber Raman resonator.

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    Published on: April 4, 2016

    Area of Science:

    • Photonics
    • Laser Physics
    • Optical Engineering

    Background:

    • Raman lasers offer wavelength tunability for various applications.
    • Developing continuous-wave (cw) tunable lasers in the 1.1-micrometer region is challenging.
    • Fiber-based resonators provide a compact and efficient platform for laser development.

    Purpose of the Study:

    • To report the first continuous-wave (cw) tunable Raman laser operating in the 1.1-micrometer spectral region.
    • To demonstrate tunable first and second Stokes oscillation using a fiber Raman resonator.
    • To characterize the performance of the developed Raman laser system.

    Main Methods:

    • Utilized a 650-meter-long, low-loss, small-core single-mode silica fiber as the Raman gain medium.
    • Employed a prism-tuned fiber Raman resonator configuration.
    • Pumped the fiber with a 5-W continuous-wave (cw) Nd:YAG laser operating at 1.064 micrometers.
    • Incorporated separate resonator mirrors for first and second Stokes oscillation.

    Main Results:

    • Achieved tunable first Stokes oscillation from 1.085 to 1.13 micrometers.
    • Obtained tunable second Stokes oscillation from 1.15 to 1.175 micrometers.
    • Demonstrated the feasibility of cw tunable Raman laser operation in the 1.1-micrometer region.

    Conclusions:

    • The developed prism-tuned fiber Raman resonator is a viable method for generating cw tunable laser light in the 1.1-micrometer range.
    • This work establishes a new capability for tunable laser sources in this spectral region.
    • The results pave the way for potential applications in spectroscopy, sensing, and optical communications.