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Synthesis of Graphene Nanofluids with Controllable Flake Size Distributions
Published on: July 17, 2019
High-concentration, surfactant-stabilized graphene dispersions.
Mustafa Lotya1, Paul J King, Umar Khan
1School of Physics, Trinity College Dublin, Dublin 2, Ireland.
Researchers developed a scalable method for producing stable graphene dispersions in water using sonication and centrifugation. This process yields high-quality graphene flakes suitable for various applications.
Area of Science:
- Materials Science
- Nanotechnology
- Physical Chemistry
Background:
- Liquid-phase processing of graphene is crucial for its scalable applications.
- Achieving high concentrations of stable graphene dispersions remains a challenge.
Purpose of the Study:
- To present a method for producing stable, high-concentration graphene dispersions in water.
- To characterize the properties of graphene flakes produced by this method.
- To evaluate the scalability and potential applications of the produced dispersions.
Main Methods:
- Graphene oxide was dispersed in water with sodium cholate surfactant.
- Low power sonication was applied for extended periods (up to 400 hours).
- Centrifugation was used to isolate and purify the graphene dispersions.
Main Results:
- Stable graphene dispersions were achieved at concentrations up to 0.3 mg/mL.
- Graphene flakes consisted of 1-10 stacked monolayers, with an average of 4.
- Flake dimensions (approx. 1 µm length, 400 nm width) were stable, with minimal defects for centrifugation rates below 2000 rpm.
- Dispersions could be cast into high-quality free-standing films.
Conclusions:
- The developed method offers a scalable approach for liquid-phase processing of graphene.
- The resulting graphene dispersions are suitable for fabricating high-quality films.
- This technique broadens the scope for graphene utilization in diverse technological applications.
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