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Reversible self-assembly of dendrimer based on polyhedral oligomeric silsesquioxanes (POSS)

Xin Wang1, Vuthichai Ervithayasuporn, Yanhong Zhang

  • 1School of Materials Science, Japan Advanced Institute of Science and Technology, 1-1 Asahidai, Nomi, Ishikawa 923-1292, Japan. tsukixin116@hotmail.com

Chemical Communications (Cambridge, England)
|November 25, 2010
PubMed

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The Diels–Alder reaction is an example of a thermal pericyclic reaction between a conjugated diene and an alkene or alkyne, commonly referred to as a dienophile. The reaction involves a concerted movement of six π electrons, four from the diene and two from the dienophile, forming an unsaturated six-membered ring. As a result, these reactions are classified as [4+2] cycloadditions.