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Related Concept Videos

Conformations of Butane02:20

Conformations of Butane

Unlike ethane and propane that have only two major conformations, butane has more than two conformers. The staggered form of butane in which the bulky methyl groups on the two carbons are placed on opposite sides, that is, at a dihedral angle of 180°, is the lowest energy, most stable form — called the anti conformer. This conformation is stabilized due to the absence of steric repulsion between the largely spaced out methyl groups. The other two staggered conformations are degenerate and have...
π Molecular Orbitals of 1,3-Butadiene01:24

π Molecular Orbitals of 1,3-Butadiene

Conjugated dienes have lower heats of hydrogenation than cumulated and isolated dienes, making them more stable. The enhanced stabilization of conjugated systems can be understood from their π molecular orbitals.
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...
Prochirality02:05

Prochirality

The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
Hydroboration-Oxidation of Alkenes03:08

Hydroboration-Oxidation of Alkenes

In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
Nomenclature of Aromatic Compounds with Multiple Substituents01:11

Nomenclature of Aromatic Compounds with Multiple Substituents

When more than one substituent is present on the benzene ring, the IUPAC nomenclature depends on the number of substituents present.
For disubstituted benzene derivatives, with two groups attached to the benzene ring, three constitutional isomers are possible. For example, consider dimethyl benzene, often called xylene, where the second methyl group can be substituted at the second, third, or fourth carbon. The relative position of the substituents is represented by prefixes ortho, meta, or...
Electrophilic 1,2- and 1,4-Addition of X2 to 1,3-Butadiene01:14

Electrophilic 1,2- and 1,4-Addition of X2 to 1,3-Butadiene

Electrophilic addition of halogens to alkenes proceeds via a cyclic halonium ion to form a 1,2-dihalide or a vicinal dihalide.

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Bis(2-chloro-1,10-phenanthroline-κN,N')(thio-cyanato-κN)zinc (2-chloro-1,10-phenanthroline-κN,N')tris-(thio-cyanato-κN)zincate.

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[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN)-1,10-phenanthroline-κN,N']bis-(nitrito-κO,O')cadmium(II).

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Related Experiment Video

Updated: Jun 5, 2026

Efficient Construction of Drug-like Bispirocyclic Scaffolds Via Organocatalytic Cycloadditions of α-Imino γ-Lactones and Alkylidene Pyrazolones
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2,3-Bis(pyrazin-2-yloxyimino)butane.

Lin Yan Yang1, Jing Min Shi

  • 1Department of Chemistry, Shandong Normal University, Jinan 250014, People's Republic of China.

Acta Crystallographica. Section E, Structure Reports Online
|January 5, 2011
PubMed
Summary

The crystal structure of C(12)H(12)N(6)O(2) was determined. All non-hydrogen atoms were found to be nearly in the same plane, lying on a crystallographic inversion center.

Area of Science:

  • Crystallography
  • Molecular Structure
  • Organic Chemistry

Background:

  • Understanding molecular geometry is crucial in chemistry.
  • Crystallographic studies reveal precise atomic arrangements.
  • The molecule C(12)H(12)N(6)O(2) was synthesized and selected for structural analysis.

Purpose of the Study:

  • To determine the three-dimensional structure of C(12)H(12)N(6)O(2).
  • To analyze the planarity and symmetry of the molecule.
  • To provide crystallographic data for this specific organic compound.

Main Methods:

  • Single-crystal X-ray diffraction was employed.
  • The crystal structure was solved and refined.
  • Analysis of atomic coordinates and bond parameters was performed.

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Main Results:

  • The molecular formula was confirmed as C(12)H(12)N(6)O(2).
  • The molecule was found to reside on a crystallographic inversion center.
  • All non-hydrogen atoms exhibited a nearly planar arrangement.

Conclusions:

  • The crystal structure of C(12)H(12)N(6)O(2) reveals a highly symmetrical and planar molecular geometry.
  • The observed planarity is likely influenced by the crystallographic symmetry.
  • This structural data contributes to the understanding of organic molecules with similar frameworks.