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Maskless fabrication of nanowells using chemically reactive colloids
Neetu Chaturvedi1, Erik Hsiao, Darrell Velegol
1Department of Chemical Engineering, Pennsylvania State University , University Park, Pennsylvania 16802, USA.
Nano Letters
|January 6, 2011
Summary
This study presents a maskless method for creating silicon nanowells using reactive nanoparticles. This technique precisely controls nanowell size and shape, offering a simple, cost-effective approach for nanofabrication.
Area of Science:
- Materials Science
- Nanotechnology
- Surface Chemistry
Background:
- Traditional nanofabrication often requires complex masks and processes.
- Precise control over nanoscale features is crucial for advanced applications.
Purpose of the Study:
- To develop a maskless, cost-effective method for fabricating nanowells on silicon substrates.
- To demonstrate precise control over nanowell dimensions and morphology.
Main Methods:
- Utilized amidine-functionalized polystyrene latex (APSL) nanoparticles on silicon wafers.
- Induced localized etching of silicon via hydrolysis of APSL amidine groups.
- Controlled nanowell dimensions by varying APSL particle diameter.
Main Results:
- Successfully fabricated nanowells with dimensions dictated by nanoparticle size.
- Achieved different nanowell shapes (inverted pyramids on Si(100), hexagonal pits on Si(111)).
- Demonstrated a high-throughput, maskless fabrication process.
Conclusions:
- The described method offers a simple, inexpensive, and safe approach to nanowell fabrication.
- This technique enables precise control over nanowell geometry on silicon surfaces.
- Opens new avenues for applications involving localized chemistry delivery from nanoparticles.

