Related Experiment Video
Updated: Jun 3, 2026

04:51
Comparison of Two Different Synthesis Methods of Single Crystals of Superconducting Uranium Ditelluride
Published on: July 8, 2021
Field re-entrant hidden-order phase under pressure in URu2Si2.
D Aoki1, F Bourdarot, E Hassinger
1INAC/SPSMS, CEA-Grenoble, 17 rue des Martyrs, F-38054 Grenoble, France. dai.aoki@cea.fr
Summary
High-quality URu2Si2 single crystals revealed a hidden-order phase reappearing under magnetic fields. Researchers mapped the pressure-temperature-field phase diagram, detailing paramagnetic, hidden-order, and antiferromagnetic states.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Quantum Materials
Background:
- URu2Si2 is a prototypical heavy-fermion compound exhibiting complex electronic phases.
- Understanding the interplay between hidden order, antiferromagnetism, and superconductivity is crucial for novel quantum materials.
Purpose of the Study:
- To investigate the pressure-temperature-field phase diagram of URu2Si2.
- To elucidate the conditions under which the hidden-order phase reappears.
- To characterize the superconducting properties in relation to other phases.
Main Methods:
- Growth of high-quality URu2Si2 single crystals.
- Thermal expansion measurements under applied pressure.
- Magnetic field application along the [001] direction.
- AC specific heat measurements to determine the upper critical field (Hc2).
Main Results:
- The hidden-order phase was observed to reappear upon suppression of the antiferromagnetic phase above a critical pressure (Px).
- A detailed pressure-temperature-field phase diagram was constructed, delineating paramagnetic, hidden-order, and antiferromagnetic regions.
- The temperature dependence of the upper critical field (Hc2) was determined for different crystallographic directions, confirming bulk superconductivity.
Conclusions:
- The study provides critical insights into the complex phase competition in URu2Si2.
- The reappearance of the hidden-order phase highlights its distinct nature and sensitivity to external stimuli.
- The findings contribute to a deeper understanding of superconductivity in correlated electron systems.
More Related Videos
Related Concept Videos
The Phase Rule
The phase rule describes the relationship between the variance (degrees of freedom), the number of components, and the number of phases in a system at equilibrium.Variance is a concept that denotes the number of independent intensive properties (properties are those that do not depend on the amount of material in the system), such as temperature, pressure, and composition, that can be altered without impacting the number of phases in equilibrium.In a single-component system, such as pure water,...
Phase Transitions: Sublimation and Deposition
Some solids can transition directly into the gaseous state, bypassing the liquid state, via a process known as sublimation. At room temperature and standard pressure, a piece of dry ice (solid CO2) sublimes, appearing to gradually disappear without ever forming any liquid. Snow and ice sublimate at temperatures below the melting point of water, a slow process that may be accelerated by winds and the reduced atmospheric pressures at high altitudes. When solid iodine is warmed, the solid sublimes...
Phase Diagram
The phase of a given substance depends on the pressure and temperature. Thus, plots of pressure versus temperature showing the phase in each region provide considerable insights into the thermal properties of substances. Such plots are known as phase diagrams. For instance, in the phase diagram for water (Figure 1), the solid curve boundaries between the phases indicate phase transitions (i.e., temperatures and pressures at which the phases coexist).
Phase Diagram
A phase diagram is a graphical representation of the physical states of a substance under different conditions of temperature and pressure. It shows the boundaries between solid, liquid, and gas phases and the conditions at which these phases coexist in equilibrium. An area in a phase diagram represents a single phase, whereas lines or phase boundaries represent the equilibrium between two phases.In the phase diagram of water, the boundary line between the solid and liquid states illustrates...
Crystal Field Theory - Octahedral Complexes
Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Phase Transitions
Whether solid, liquid, or gas, a substance's state depends on the order and arrangement of its particles (atoms, molecules, or ions). Particles in the solid pack closely together, generally in a pattern. The particles vibrate about their fixed positions but do not move or squeeze past their neighbors. In liquids, although the particles are closely spaced, they are randomly arranged. The position of the particles are not fixed—that is, they are free to move past their neighbors to occupy...

