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Updated: Jun 1, 2026

Synthesis of a Water-soluble Metal–Organic Complex Array
Published on: October 8, 2016
Bromido(2,2':6',2''-terpyridine)platinum(II) dibromidoaurate(I) dimethyl sulfoxide solvate
Abstract:
The crystal structure of the title compound, [PtBr(C(15)H(11)N(3))][AuBr(2)]·(CH(3))(2)SO, exhibits infinite chains of {PtAuPt}(∞) metallophilic inter-actions along the b axis. Two cations and one anion stack in a trimer with a unique Pt⋯Au distance of 3.3361 (5) Å and Pt⋯Pt contacts of 3.4335 (6) Å. The remaining [AuBr(2)](-) anion forms no close contacts.
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