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Updated: May 29, 2026

Preparation and Characterization of C60/Graphene Hybrid Nanostructures
Published on: May 15, 2018
Molecular catalysis for fullerene functionalization
1Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan. itami.kenichiro@a.mbox.nagoya-u.ac.jp
Abstract:
This account highlights elements of our efforts to explore new functionalization chemistry of fullerenes using molecular catalysts since 2006. These endeavors have led to the development of new reactions such as (i) organoboron addition to fullerenes, (ii) C-H bond allylation and arylation of organo(hydro)fullerenes, (iii) C-H/C-C bond cleavage of alkynyl(hydro)fullerenes, (iv) regioselective tetraallylation of fullerenes, (v) double nucleophilic substitution of aziridinofullerene, and (vi) [2+2] cycloaddition of aziridinofullerene with alkynes. These works not only highlight the potential of molecular catalysis for fullerene functionalization, but also unlock opportunities for markedly different strategies in nanocarbon synthesis.
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