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Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks
Adam F Gross1, Elena Sherman, John J Vajo
1HRL Laboratories, LLC, Malibu, CA 90265, USA. afgross@hrl.com
Dalton Transactions (Cambridge, England : 2003)
|March 13, 2012
Abstract:
Sodalite zeolitic imidazolate frameworks containing Co (ZIF-67) and Zn (ZIF-8) were synthesized at room temperature under aqueous conditions in 10 min. A trialkylamine deprotonated the 2-methylimidazole ligand and nucleated the frameworks. Furthermore, the ligand acted as a structure directing agent in place of an organic solvent.
