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Two triazole-based metal-organic frameworks constructed from nanosized Cu20 and Cu30 wheels
Chan-Zi Ruan1, Ru Wen, Min-Xia Liang
1State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Inorganic Chemistry
|June 29, 2012
Abstract:
Two metal-organic frameworks constructed from nanosized Cu(20) and Cu(30) wheels have been obtained under hydrothermal conditions based on 1,2,3-triazole and 1-H-1,2,3-benzotriazole, respectively. Crystal structure analysis shows that their differences in the size and nuclearity of Cu(20) and Cu(30) wheels are attributed to the steric effect of ligands.
