Related Experiment Video
Updated: May 19, 2026

Synthesis of Metal Nanoparticles Supported on Carbon Nanotube with Doped Co and N Atoms and its Catalytic Applications in Hydrogen Production
Published on: December 6, 2021
In situ-generated metal oxide catalyst during CO oxidation reaction transformed from redox-active metal-organic
Jin Yeong Kim1, Mingshi Jin, Kyung Joo Lee
1Interdisciplinary School of Green Energy and KIER-UNIST Advanced Center for Energy, Ulsan National Institute of Science and Technology (UNIST), UNIST-gil 50, Ulsan, 689-798, Republic of Korea. shjoo@unist.ac.kr.
Abstract:
The preparation of redox-active metal-organic framework (ra-MOF)-supported Pd nanoparticles (NPs) via the redox couple-driven method is reported, which can yield unprotected metallic NPs at room temperature within 10 min without the use of reducing agents. The Pd@ra-MOF has been exploited as a precursor of an active catalyst for CO oxidation. Under the CO oxidation reaction condition, Pd@ra-MOF is transformed into a PdOx-NiOy/C nanocomposite to generate catalytically active species in situ, and the resultant nanocatalyst shows sustainable activity through synergistic stabilization.
More Related Videos
Related Concept Videos
Heterogeneous Catalysis
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide

