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Updated: May 17, 2026

Low-energy Cathodoluminescence for (Oxy)Nitride Phosphors
Published on: November 15, 2016
A novel phosphor for glareless white light-emitting diodes.
Hisayoshi Daicho1, Takeshi Iwasaki, Kiminori Enomoto
1Department of Research and Development, Koito Manufacturing Co., Ltd, Shizuoka 424-8764, Japan. hdaicho@koito.co.jp
Researchers developed a novel glareless white light-emitting diode (LED) using a unique yellow-emitting phosphor. This innovation enhances visual comfort for next-generation illumination by reducing uncomfortable glare from high-luminance LEDs.
Area of Science:
- Materials Science
- Solid-State Lighting
- Photonics
Background:
- White light-emitting diodes (LEDs) offer high luminous efficiency for next-generation illumination.
- Current high-luminance white LEDs cause visual discomfort due to glare from small emission areas.
- There is a need for glareless lighting solutions to improve user experience.
Purpose of the Study:
- To develop a novel glareless white LED technology.
- To introduce a new yellow-emitting phosphor for improved LED lighting.
- To address the issue of glare in high-luminance white LEDs.
Main Methods:
- Synthesis and characterization of a novel Eu(2+)-doped chlorometasilicate phosphor: (Ca(1-x-y,)Sr(x,)Eu(y))(7)(SiO(3))(6)Cl(2).
- Investigation of the phosphor's luminescence properties, including its large Stokes shift and low blue absorption.
- Fabrication of white LEDs using the developed phosphor, a blue-emitting phosphor, and a violet chip.
Main Results:
- The synthesized (Ca(1-x-y,)Sr(x,)Eu(y))(7)(SiO(3))(6)Cl(2) phosphor efficiently converts violet light to yellow luminescence.
- Phosphors based on this host material exhibit significantly reduced blue absorption compared to conventional phosphors.
- Fabricated white LEDs demonstrate glareless properties with large emission areas suitable for general illumination.
Conclusions:
- The Eu(2+)-doped chlorometasilicate phosphor is effective in creating glareless white LEDs.
- This new phosphor technology offers a solution to visual discomfort caused by current LED glare.
- The developed glareless white LEDs are suitable for general illumination applications, improving visual comfort.
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