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Updated: May 12, 2026

Colloidal Synthesis of Nanopatch Antennas for Applications in Plasmonics and Nanophotonics
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Oriented assembly of polyhedral plasmonic nanoparticle clusters.

Joel Henzie1, Sean C Andrews, Xing Yi Ling

  • 1Department of Chemistry, University of California, Berkeley, CA 94720, USA.

Proceedings of the National Academy of Sciences of the United States of America
|April 10, 2013
PubMed
Summary
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Noble metal nanostructures, like silver polyhedra, self-assemble into precise clusters for advanced optical properties. This enables the development of scalable and reliable chemical sensors using surface-enhanced Raman spectroscopy (SERS).

Area of Science:

  • Nanotechnology
  • Materials Science
  • Plasmonics

Background:

  • Shaped colloids serve as nanoscale building blocks for bottom-up material construction.
  • Noble metal nanostructures exhibit unique optical properties dependent on precise structural control.
  • Understanding surface plasmon behavior in nanoparticle clusters is crucial for sensor development.

Purpose of the Study:

  • To examine local surface plasmon resonances in different arrangements of silver polyhedral clusters.
  • To develop a scalable method for constructing nanoparticle clusters for sensor applications.
  • To investigate the relationship between cluster structure and SERS enhancement factors.

Main Methods:

  • Experimental investigation of silver polyhedral cluster assemblies.

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A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
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Last Updated: May 12, 2026

Colloidal Synthesis of Nanopatch Antennas for Applications in Plasmonics and Nanophotonics
09:12

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Published on: May 28, 2016

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
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Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

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A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

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  • Computational simulation of local surface plasmon resonances.
  • High-resolution transmission electron microscopy (HR-TEM) for structural analysis.
  • Development of a gravity-driven assembly method using patterned templates.
  • Main Results:

    • Monodisperse, atomically smooth silver polyhedra self-assemble with uniform interparticle gaps.
    • Reproducible SERS enhancement factors were observed across different assemblies.
    • A gravity-driven method allows for the generation of arbitrary nanoparticle clusters based on template design.
    • Systematic examination of cluster arrangements and their impact on SERS performance.

    Conclusions:

    • Precise control over nanoparticle arrangement leads to optimized optical properties for SERS.
    • The developed assembly method facilitates the creation of scalable and reliable SERS sensors.
    • Self-assembled silver polyhedral clusters offer a promising platform for advanced chemical and biochemical sensing.