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Stereodivergent synthesis of (+)- and (-)-isolineatin
Laura Pérez1, Ramon Alibés, Pedro de March
1Departament de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Spain.
The Journal of Organic Chemistry
|April 16, 2013
Abstract:
A stereodivergent approach to (+)- and (-)-isolineatin using (S)-4-methyl-5-pivaloyloxymethyl-2(5H)-furanone as the single source of asymmetry by exploiting the inherent chirality at the C-5 stereocenter is described.
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