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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

Palladium-catalyzed C-H arylation using phosphoramidate as a directing group at room temperature

Bathoju Chandra Chary1, Sunggak Kim, Youngchul Park

  • 1Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.

Organic Letters
|May 21, 2013
PubMed
Summary

Researchers developed a novel phosphoramidate directing group enabling efficient arylation via selective C-H bond activation. This breakthrough allows for the synthesis of diverse N-aryl phosphoramidates under mild, room-temperature conditions.

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