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Related Concept Videos

¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene π orbitals.

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Plasmonic Trapping and Release of Nanoparticles in a Monitoring Environment
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Published on: April 4, 2017

Deep-subwavelength plasmonic nanoresonators exploiting extreme coupling.

Rasoul Alaee1, Christoph Menzel, Uwe Huebner

  • 1Institute of Condensed Matter Theory and Solid State Optics, Friedrich-Schiller-Universität Jena, Jena, Germany. rasoul.alaee@uni-jena.de

Nano Letters
|June 29, 2013
PubMed
Summary
This summary is machine-generated.

Researchers achieved deep-subwavelength plasmonic devices using ultra-thin dielectric spacers in metal-insulator-metal (MIM) waveguides. This breakthrough enables advanced applications in metamaterials and sensing.

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Area of Science:

  • Plasmonics and Nanophotonics
  • Materials Science

Background:

  • Metal-insulator-metal (MIM) waveguides are fundamental to plasmonic devices.
  • Existing nanoresonators often fail to achieve deep-subwavelength dimensions due to thick dielectric spacers.
  • This limitation hinders strong deviation of surface plasmon polariton wavevectors from the light line.

Purpose of the Study:

  • To demonstrate a method for fabricating deep-subwavelength plasmonic nanoresonators.
  • To overcome the limitations imposed by conventional dielectric spacer thicknesses.
  • To explore the potential of an extreme coupling regime in MIM waveguides.

Main Methods:

  • Fabrication of MIM nanoresonators with few-nanometer-thick dielectric spacers using atomic layer deposition.
  • Experimental characterization of the fabricated devices.
  • Numerical simulations and analytical modeling to support experimental findings.

Main Results:

  • Achieved deep-subwavelength perfect absorbers by exploiting an extreme coupling regime.
  • Demonstrated that ultra-thin dielectric spacers (few nanometers) lift previous limitations.
  • Experimental results are in excellent agreement with theoretical and numerical predictions.

Conclusions:

  • Exploiting extreme coupling in MIM waveguides with ultra-thin spacers enables deep-subwavelength plasmonics.
  • This approach facilitates the development of advanced functional plasmonic devices.
  • Potential applications include metamaterials, light harvesting, sensing, and quantum-plasmonic devices.