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A novel CO2-stable dual phase membrane with high oxygen permeability
Fangyi Liang1, Huixia Luo, Kaveh Partovi
1Institute of Physical Chemistry and Electrochemistry, Leibniz University of Hannover, Callinstr. 3a, D-30167 Hannover, Germany. fangyi.liang@pci.uni-hannover.de.
Summary
Cobalt-doping a dual-phase membrane (CP-PSFC) enhances its CO2 stability and oxygen permeability. This makes CP-PSFC a promising material for carbon capture in oxyfuel applications.
Area of Science:
- Materials Science
- Chemical Engineering
- Environmental Science
Background:
- Mixed ionic-electronic conducting (MIEC) materials are crucial for oxygen separation membranes.
- Praseodymium cerate (PrCeO) and strontium cobalt ferrite (SrCoFe) based materials have shown potential but face challenges in stability and permeability.
- Developing dual-phase membranes can combine the advantages of different material phases.
Purpose of the Study:
- To investigate the effect of cobalt-doping on the properties of a dual-phase membrane composed of Ce(0.9)Pr(0.1)O(2-δ) and Pr(0.6)Sr(0.4)Fe(0.5)Co(0.5)O(3-δ).
- To evaluate the CO2 stability and oxygen permeability of the cobalt-doped dual-phase membrane (CP-PSFC).
- To assess the potential of CP-PSFC as a membrane for CO2 capture in the oxyfuel process.
Main Methods:
- Synthesis of the dual-phase membrane by incorporating cobalt into the Pr(0.6)Sr(0.4)Fe(0.5)Co(0.5)O(3-δ) phase.
- Characterization of the membrane's structural and chemical properties.
- Measurement of oxygen permeability and CO2 stability under relevant conditions for the oxyfuel process.
Main Results:
- Cobalt-doping of the Pr(0.6)Sr(0.4)Fe(0.5)Co(0.5)O(3-δ) phase in the dual-phase membrane (CP-PSFC) resulted in a favorable combination of properties.
- The CP-PSFC membrane exhibited high CO2 stability.
- The CP-PSFC membrane demonstrated high oxygen permeability.
Conclusions:
- The cobalt-doped dual-phase membrane (CP-PSFC) shows excellent CO2 stability and high oxygen permeability.
- CP-PSFC is a promising candidate membrane material for industrial applications in CO2 capture via the oxyfuel process.
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