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Updated: Apr 30, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
tBu3P-Coordinated 2-Phenylaniline-Based Palladacycle Complex As Precatalyst for Pd-Catalyzed Coupling Reactions of
Hong-Hai Zhang1, Jie Dong1, Qiao-Sheng Hu1
1Department of Chemistry, College of Staten Island and Graduate Center of the City University of New York, Staten Island, New York, 10314, United States.
Abstract:
tBu3P-Coordinated 2-phenylaniline-based palladacycle complex was demonstrated to be an efficient precatalyst for Pd-catalyzed coupling reactions of aryl halides with polyfluoroarenes via C-H activation strategy. The readily accessibility and easy handling nature of tBu3P- coordinated 2-aminobiphenyl-based palladacycle complex and the high yields of the reaction makes tBu3P-coordinated 2-aminobiphenyl-based palladacycle complex an attractive precatalyst for the cross-coupling reaction of aryl halides with polyfluoroarenes.
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