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Updated: Apr 29, 2026

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
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Covalent surface modification of oxide surfaces.

Sidharam P Pujari1, Luc Scheres, Antonius T M Marcelis

  • 1Laboratory of Organic Chemistry, Wageningen University, P.O. Box 26, 6703 HB Wageningen (The Netherlands).

Angewandte Chemie (International Ed. in English)
|May 23, 2014
PubMed
Summary
This summary is machine-generated.

This review explores robust surface modification techniques for oxides using covalent attachment of monolayers. This method offers precise control over surface properties for applications in optoelectronics and biosensing.

Keywords:
covalent bondsmonolayersoxidesreaction mechanismssurface chemistry

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Area of Science:

  • Materials Science
  • Surface Chemistry
  • Nanotechnology

Background:

  • Tuning surface properties is crucial for advanced devices.
  • Down-sizing components increases surface area/volume ratio, demanding better surface control.
  • Applications include tuning wettability and creating specific biomolecular interactions.

Purpose of the Study:

  • To present a method for robust surface modification of oxides.
  • To enable precise tuning of surface properties for specific applications.
  • To review the covalent attachment of monolayers as a key technique.

Main Methods:

  • Covalent attachment of monolayers onto oxide surfaces.
  • Deposition of robust overlayers to modify substrate properties.
  • Surface functionalization for tailored interactions.

Main Results:

  • Achieved robust and long-lasting surface modifications.
  • Demonstrated control over surface properties like wettability.
  • Enabled specific binding for biosensing applications.

Conclusions:

  • Covalent attachment of monolayers is an effective strategy for robust surface modification of oxides.
  • This approach provides precise control over surface properties for optoelectronic and biosensing applications.
  • The technique offers long-lasting and highly specific surface tuning.