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Site-selective photodeposition of Pt on a particulate Sc-La5Ti2CuS5O7 photocathode: evidence for one-dimensional
Guijun Ma1, Jingyuan Liu, Takashi Hisatomi
1Department of Chemical System Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan. domen@chemsys.t.u-tokyo.ac.jp.
Abstract:
Photodeposition of Pt on the Sc-doped La5Ti2CuS5O7 (Sc-LTC) photocathode, a visible-light-responsive semiconducting oxysulfide, is accomplished in a solution containing H2PtCl6 and K2C2O4. Pt particles are selectively deposited on the top surface of rod-like Sc-LTC particles as a result of one-dimensional transfer of photogenerated electrons.

