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Synthesis of Programmable Main-chain Liquid-crystalline Elastomers Using a Two-stage Thiol-acrylate Reaction
Published on: January 19, 2016
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Programmable and adaptive mechanics with liquid crystal polymer networks and elastomers
Timothy J White1, Dirk J Broer2
1Air Force Research Laboratory, Materials and Manufacturing Directorate, Wright-Patterson Air Force Base, Ohio 45433, USA.
Nature Materials
|October 23, 2015
Summary
Researchers are exploring liquid crystalline polymers for novel mechanical responses beyond displays. This review details their development, focusing on thermal and light-induced shape changes and topographical control for new applications.
Area of Science:
- Materials Science
- Polymer Chemistry
- Condensed Matter Physics
Background:
- Liquid crystals are foundational to modern display technology.
- The commoditization of displays drives research into new applications for liquid crystalline materials.
- Polymeric liquid crystals offer unique properties and stimuli-responsive behaviors.
Purpose of the Study:
- To review the historical development of liquid crystalline polymers.
- To highlight macroscale mechanical responses (bending, twisting, buckling) induced by thermal and photogenerated stimuli.
- To discuss local-feature development and topographical control in liquid crystalline polymers.
Main Methods:
- Historical review of liquid crystalline polymer research.
- Analysis of thermally and photogenerated macroscale mechanical responses.
- Examination of local-feature development and topographical control.
Main Results:
- Liquid crystalline polymers exhibit fascinating and useful properties beyond traditional display applications.
- Macroscale mechanical responses like bending, twisting, and buckling are key features.
- Topographical control through local-feature development is a significant area of study.
Conclusions:
- Liquid crystalline polymers offer distinct advantages for stimuli-induced mechanical responses.
- Further research is needed to overcome existing challenges.
- Near-term application opportunities exist in various fields.

