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Expanding the light absorption of poly(3-hexylthiophene) by end-functionalization with π-extended porphyrins
Michèle Chevrier1, Sébastien Richeter2, Olivier Coulembier3
1Institut Charles Gerhardt, Université de Montpellier, Place Eugène Bataillon, 34095 Montpellier Cedex 05, France. sebastien.clement1@umontpellier.fr and Service des Matériaux Polymères et Composites (SMPC), Centre d'Innovation et de Recherche en Matériaux et Polymères (CIRMAP), Université de Mons, 20 Place du Parc, 7000 Mons, Belgium.
Abstract:
Poly(3-hexylthiophene)s end-functionalized with π-extended porphyrins have been synthesized in a one-pot procedure. The polymers show a broad absorption profile extending to 700 nm and a fibrillar microstructure, which can be tuned through judicious selection of the porphyrin molar ratio.
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