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Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
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Enantiopure anion templated synthesis of a zeolitic metal-organic framework
Zhong-Xuan Xu1, Yu-Lu Ma2, Jian Zhang3
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China. zhj@fjirsm.ac.cn and Department of Chemistry, Zunyi Normal College, Zunyi, Guizhou 563002, P. R. China.
Chemical Communications (Cambridge, England)
|December 19, 2015
Abstract:
Utilizing (R)-H3CIA as a chiral template, an unprecedented homochiral metal-organic framework (MOF) with zeotype GIS topology is obtained from achiral 1.4-DIB ligands and Zn(II) ions, which opens up a feasible approach to create zeolitic MOFs with homochirality.
