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Updated: Mar 24, 2026

Synthesis and Exfoliation of Discotic Zirconium Phosphates to Obtain Colloidal Liquid Crystals
Published on: May 25, 2016
Surface modification of layered zirconium phosphate with PNIPAM
Xuezhen Wang1, Di Zhao, Ilse B Nava Medina
1Artie McFerrin Department of Chemical Engineering, Texas A&M University, College Station, TX 77843-3122, USA. zcheng@tamu.edu.
Abstract:
A new method was reported to modify layered zirconium phosphate (ZrP) with thermoresponsive polymer PNIPAM (poly N-isopropylacrylamide). PNIPAM was proved to be covalently grafted onto ZrP. (60)Co γ-rays irradiation produced peroxide groups on the surface which, upon heating, initiated free radical polymerization and subsequent attachment of PNIPAM.
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