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Transition-sized Au92 nanoparticle bridging non-fcc-structured gold nanoclusters and fcc-structured gold nanocrystals
Lingwen Liao1, Jishi Chen1, Chengming Wang2
1Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei, Anhui 230031, China. zkwu@issp.ac.cn.
Abstract:
Herein, we report the intriguing structure, optical absorption and electrochemical properties of the transition-sized Au92(TBBT)44 (Au92 for short, TBBT = 4-tert-butylbenzenethiolate) nanoparticle. An interesting observation is the 4H phase array of Au92 nanoparticles in the unit cells of single crystals.

