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Nuclear spin-lattice relaxation in nitroxide spin-label EPR

Derek Marsh1

  • 1Max-Planck-Institut für biophysikalische Chemie, 37070 Göttingen, Germany; University of Southern Denmark, MEMPHYS-Centre for Biomembrane Physics, Campusvej 55, 5230 Odense M, Denmark.

Journal of Magnetic Resonance (San Diego, Calif. : 1997)
|October 8, 2016
PubMed
Summary

This study redefines the nuclear relaxation rate for nitrogen-14 nitroxyl spin labels, ensuring consistency between continuous-wave Electron Paramagnetic Resonance (CW-EPR) and pulsed EPR measurements. This revised definition improves the accuracy of nuclear relaxation time analysis.

Keywords:
(15)N-, (14)N-nitroxidesELDORElectron-nuclear dipolar (END)Saturation recovery

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