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Updated: Mar 7, 2026

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
Published on: May 20, 2014
Non-equilibrium concentration fluctuations in superparamagnetic nanocolloids
Ana Oprisan1, Ashley Rice2, Sorinel A Oprisan2
1College of Charleston, Department of Physics and Astronomy, Charleston, SC, USA. oprisana@cofc.edu.
Abstract:
We investigate non-equilibrium concentration fluctuations during the free diffusion of a colloidal suspension against pure water. We investigate Fe2O3 superparamagnetic nanocolloids with sizes between 1 and 10 nm by means of a shadowgraph apparatus to determine the mixture mass diffusion coefficient and kinematic viscosity. The experiments were performed in three distinct conditions: Experiment 1 is without any magnetic field; Experiment 2 with a vertical magnetic field; Experiment 3 after turning off the magnetic field. We found no correlation between the kinematic viscosity coefficient and the external magnetic field. Conversely, we found that the mass diffusion coefficient decreases in the presence of the external magnetic field and slowly rebounds after the magnetic field was turned off.
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