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Published on: July 3, 2015
Thermal Stability and Magnetic Properties of Polyvinylidene Fluoride/Magnetite Nanocomposites
Zen-Wei Ouyang1, Erh-Chiang Chen2, Tzong-Ming Wu3
1Department of Materials Science and Engineering, National Chung Hsing University, 250, Kuo Kuang Road, Taichung 402, Taiwan. redfish20614@hotmail.com.
Abstract:
This work describes the thermal stability and magnetic properties of polyvinylidene fluoride (PVDF)/magnetite nanocomposites fabricated using the solution mixing technique. The image of transmission electron microscopy for PVDF/magnetite nanocomposites reveals that the 13 nm magnetite nanoparticles are well distributed in PVDF matrix. The electroactive β-phase and piezoelectric responses of PVDF/magnetite nanocomposites are increased as the loading of magnetite nanoparticles increases. The piezoelectric responses of PVDF/magnetite films are extensively increased about five times in magnitude with applied strength of electrical field at 35 MV/m. The magnetic properties of PVDF/magnetite nanocomposites exhibit supermagnetism with saturation magnetization in the range of 1.6 × 10-3-3.1 × 10-3 emu/g, which increases as the amount of magnetite nanoparticles increases. The incorporation of 2 wt % magnetite nanoparticles into the PVDF matrix improves the thermal stability about 25 °C as compared to that of PVDF. The effect of magnetite particles on the isothermal degradation behavior of PVDF is also investigated.
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