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Updated: Feb 24, 2026

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Published on: October 24, 2017
Charging assisted structural phase transitions in monolayer InSe.
Liangzhi Kou1, Aijun Du, Yandong Ma
1School of Chemistry, Physics and Mechanical Engineering Faculty, Queensland University of Technology, Garden Point Campus, QLD 4001, Brisbane, Australia. Liangzhi.kou@qut.edu.au.
Researchers discovered two new phases of Indium Selenide (InSe) monolayer using first-principles calculations. These phases, α and γ, exhibit unique electronic properties and can be stabilized by charging effects, opening new avenues for 2D material applications.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Solid-State Chemistry
Background:
- Indium Selenide (InSe) monolayer is a 2D material with promising electronic and transport properties.
- Its intricate atomic structure allows for modulation of crystal and electronic properties.
Purpose of the Study:
- To identify new structural phases of monolayer InSe beyond the known β phase.
- To investigate the electronic properties and stability of these newly identified phases.
- To explore the role of charging effects in phase transitions and stabilization.
Main Methods:
- First-principles calculations were employed to explore the structural and electronic properties of InSe.
- The study focused on identifying distinct atomic configurations and their corresponding electronic band structures.
- Simulations investigated the influence of external factors like electron injection and substrate coupling on phase stability.
Main Results:
- Two new phases, designated α and γ, were identified in addition to the existing β phase of monolayer InSe.
- The α phase exhibits electronic properties comparable to the β phase.
- The γ phase displays exotic quantum spin Hall states and Dirac cones in its electronic structure.
- Charging effects were found to be crucial for stabilizing the α and γ phases and facilitating transitions from the β phase.
Conclusions:
- Monolayer InSe exists in multiple structural phases with distinct electronic properties.
- Charging is a key mechanism for tuning the phase stability and electronic characteristics of InSe.
- The discovery of new phases and the understanding of charging effects pave the way for novel 2D material applications.
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