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Updated: Feb 21, 2026

Scale-up Chemical Synthesis of Thermally-activated Delayed Fluorescence Emitters Based on the Dibenzothiophene-S,S-Dioxide Core
Published on: October 24, 2017
Unconventional Molecular Design Approach of High-Efficiency Deep Blue Thermally Activated Delayed Fluorescent
Jeong-A Seo1, Yirang Im1, Si Hyun Han1
1School of Chemical Engineering, Sungkyunkwan University , 2066 Seobu-ro, Jangan-gu, Suwon, Gyeonggi 440-746, Korea.
Abstract:
Unconventional blue thermally activated delayed fluorescent emitters having electron-donating type indolocarbazole as an acceptor were developed by attaching carbazolylcarbazole or acridine donors to the indolocarbazole acceptor. Three compounds were derived from the indolocarbazole acceptor. The indolocarbazole-acridine combined products showed efficient delayed fluorescent behavior and a high quantum efficiency of 19.5% with a color coordinate of (0.15, 0.16) when they were evaluated as thermally activated delayed fluorescent emitters in deep blue fluorescent devices. This is the first demonstration of the use of electron-donating carbazole-derived moieties as efficient acceptor units of blue thermally activated delayed fluorescent emitters.
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