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Silver-Catalyzed Minisci Reactions Using Selectfluor as a Mild Oxidant

Jordan D Galloway1, Duy N Mai1, Ryan D Baxter1

  • 1Department of Chemistry, Chemical Biology, University of California , 5200 North Lake Road, Merced, California 95343, United States.

Organic Letters
|October 19, 2017
PubMed
Summary

A novel silver-catalyzed Minisci reaction enables radical C-H alkylation and arylation of heteroarenes and quinones. This method efficiently utilizes mild oxidation with Selectfluor, even with sensitive radical precursors.

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