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Updated: Feb 16, 2026

The Preparation of Electrohydrodynamic Bridges from Polar Dielectric Liquids
Published on: September 30, 2014
Aromaticity switching via azulene transformations in azulene-bridged A,D-dithiahexaphyrin
Michał J Białek1, Lechosław Latos-Grażyński1
1Department of Chemistry, University of Wrocław, F. Joliot-Curie 14, 50-383 Wrocław, Poland. lechoslaw.latos-grazynski@chem.uni.wroc.pl.
Abstract:
The incorporation of an azulene bridge into an aromatic hexaphyrin framework allows manipulating π-electron delocalization pathways. The palladium(ii) complex undergoes hydroxyl-triggered azulene contraction or isomerization to an oxynaphthalene unit, transforming the hexaphyrin framework into meso-linked carbaporphyrins. This converts the 26π-electron pathway into the 18π one.
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