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Ethylene Polymerizations Using Parallel Pressure Reactors and a Kinetic Analysis of Chain Transfer Polymerization
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In-Situ Immobilization of Ni Complex on Amine-Grafted SiO₂ for Ethylene Polymerization

Sang Yun Lee1, Young Soo Ko1

  • 1Department of Chemical Engineering, Kongju National University Budaedong, Cheonan, Chungnam, 31080, Korea.

Journal of Nanoscience and Nanotechnology
|February 17, 2018
PubMed

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Various carboxylic acid derivatives (such as acid chlorides, esters, and anhydrides) can be used for the acylation of amines to yield amides. The reaction requires two equivalents of amines. The first amine molecule functions as a nucleophile and attacks the carbonyl carbon to produce a tetrahedral intermediate. This is followed by the loss of the leaving group and restoration of the C=O bond.
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