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Synthesis and Unique Optical Properties of Selenophenyl BODIPYs and Their Linear Oligomers
Daisuke Taguchi1, Takashi Nakamura1, Hiroaki Horiuchi2
1Graduate School of Pure and Applied Sciences and Tsukuba Research Center for Energy Materials Science (TREMS) , University of Tsukuba , 1-1-1 Tennodai , Tsukuba , Ibaraki 305-8571 , Japan.
Abstract:
A series of selenophene-substituted boron-dipyrrin (BODIPY) monomers and selenophene-linked BODIPY oligomers was synthesized. The synthesized BODIPYs show good absorption/emission properties in the red to near-infrared region. Furthermore, some of the selenophenyl BODIPYs are not only useful fluorophores but also good photosensitizers to produce singlet oxygen.
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