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Intermolecular σ-Bond Cross-Exchange Reaction between Cyclopropenones and (Benzo)silacyclobutanes: Straightforward
Wen-Tao Zhao1, Fang Gao1, Dongbing Zhao1
1State Key Laboratory and Institute of Elemento-Organic Chemistry, College of Chemistry, Nankai University, 94 Weijin Road, Tianjin, 300071, China.
Abstract:
Described herein is the first intermolecular σ-bond exchange reaction between the C-C bond of cyclopropenones and C-Si bond of (benzo)silacyclobutanes and it proceeds smoothly by treatment with either 1 mol % of a palladium or 2 mol % of a nickel catalyst. This reaction constitutes an unprecedented route for the synthesis of various sila(benzo)suberones. And it is also the first example of a σ-bond exchange reaction involving cyclopropenones.
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