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Structural Diversity in the Solid-State Structures of the Rubidium and Cesium Salts of 2,6-Dimesitylphenylphosphane
Gerd W Rabe1, Sohrab Kheradmandan1, Louise M Liable-Sands2
1Anorganisch-chemisches Institut der Technischen Universität München Lichtenbergstrasse 4, D-85747 Garching (Germany), Fax: (+49) 89-289-13125.
Abstract:
A coordination environment reminiscent of a paddle-wheel is exhibited by aryl groups about one of the two cesium ions in CsP(H)Dmp (Dmp=2,6-dimesitylphenyl; structure depicted on the right), which has now been synthesized and is found to exhibit Cs+ {Cs2 [P(H)Dmp]3 }- contact ion pairs in the solid state. In contrast, the analogous rubidium compound displays a Rb4 P4 cube as the central structural motif.
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