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Carbide clusterfullerene DyYTiC@C80 featuring three different metals in the endohedral cluster and its single-ion
Ariane Brandenburg1, Denis S Krylov, Alexander Beger
1Leibniz Institute for Solid State and Materials Research (IFW), D-01069 Dresden, Germany. a.popov@ifw-dresden.de.
Abstract:
Carbide clusterfullerene DyYTiC@C80-Ih with three different metal atoms in the endohedral cluster is obtained by arc-discharge synthesis with methane as reactive gas and is successfully isolated by HPLC. The compound shows single-molecule magnetism (SMM) with magnetic hysteresis below 8 K. The SMM properties of DyYTiC@C80 are compared to those of DySc2N@C80 and the influence of the central atom in the endohedral cluster is analyzed.
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