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Updated: Feb 2, 2026
Hyperspectral Imaging as a Tool to Study Optical Anisotropy in Lanthanide-Based Molecular Single Crystals
Published on: April 14, 2020
Single-ion magnetic anisotropy in a vacant octahedral Co(ii) complex
Amit Kumar Mondal1, Jesús Jover, Eliseo Ruiz
1Department of Chemistry, Indian Institute of Science Education and Research (IISER), Bhopal Bypass Road, Bhauri, Bhopal-462066, India. skonar@iiserb.ac.in.
Abstract:
The first example of a pentacoordinate CoII single-ion magnet based on a P-donor ligand with vacant octahedral coordination geometry is reported here. Thorough magnetic measurements reveal the presence of field induced slow relaxation behavior with an easy-plane magnetic anisotropy. The combined theoretical and experimental studies disclose that direct and quantum tunneling processes become dominant at low temperature to relax the magnetization; however, from the thermal dependence of relaxation time it can be observed that the optical or acoustic Raman processes become important to the overall relaxation process.
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