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Updated: Jan 27, 2026

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Published on: October 4, 2017
Synthesis, Characterization, and Functionalization of Tetrafunctional Double-Decker Siloxanes
Yujia Liu, Nobuhiro Takeda, Armelle Ouali1
1Institut Charles Gerhardt Montpellier, UMR 5253 CNRS-UM-ENSCM , 8 rue de l'Ecole Normale , 34296 Montpellier, Cedex 05 , France.
Abstract:
Novel tetravinyl- and tetraallyl-substituted closed double-decker siloxanes (DDSQs) were synthesized and characterized, and their structures were elucidated by X-ray crystallographic analysis. Moreover, it was shown that peripheral olefins could successfully undergo hydrosilylation quantitatively. Such tetrafunctionalizable DDSQs (DDSQ-Vinyl4 and DDSQ-Allyl4) thus constitute promising building blocks for more complex inorganic-organic hybrid materials.
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