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Updated: Jan 24, 2026

A Salt-Templated Synthesis Method for Porous Platinum-based Macrobeams and Macrotubes
Published on: May 18, 2020
Two-step template method for synthesis of axis-length-controlled porphyrin-containing hollow structures
Yusuke Chiba1, Yuki Oka, Hiroshi Masai
1Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.
Abstract:
π-Conjugated porphyrin-containing hollow structures with defined axis-length were successfully synthesized by a two-step template method, i.e., template-assisted cyclization and oligomerization. During the oligomerization, templates played important roles in controlling the reaction rates and the axis lengths. The hollow structures exhibited an extended effective π-conjugation because of the high coplanarity between porphyrins.
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