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Updated: Jan 22, 2026

Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Precise regulation of the selectivity of supported nano-Pd catalysts using polysiloxane coatings with tunable surface
Hongli Wang1, Ziqian Gao1, Xinzhi Wang2
1State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. China. jpzhang@licp.cas.cn fshi@licp.cas.cn.
Abstract:
A facile method was developed for surface modification of supported nano-Pd catalysts with tailorable wettability. The obtained Pd/TiO2@POS catalytic materials could be used in the controllable synthesis of styrene and ethylbenzene obtained from hydrogenation of phenylacetylene and the selective synthesis of imine and N-methylanilines via a reductive amination reaction. The precise modification of the hydrophilicity/hydrophobicity of the catalyst surface is crucial to realize this targeted transformation.
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