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Updated: Jan 20, 2026

Author Spotlight: Characterizing Porous Materials for Aiding the Development of Robust Metal-Organic Frameworks with Adsorption Behavior
Published on: March 8, 2024
On-surface synthesis of one-type pore single-crystal porous covalent organic frameworks
Zhenliang Hao1, Lingling Song1, Cuixia Yan1
1Kunming University of Science and Technology, Faculty of Materials Science and Engineering, Kunming, Yunnan 650000, P. R. China. lu.jianchen1989@gmail.com j.cai@kmust.edu.cn.
Abstract:
Employing a 1,3,5-tris(4-bromophenyl)benzene precursor as a building block, we successfully fabricate large-scale, non-multihole and single-layer pCOFs on the Ag(111) surface in a controllable manner via the on-surface reaction. We reveal that two main factors, the heating rate and growth temperature, have a strong impact on the size and quality of the pCOFs by STM. Furthermore, the band gap of the pCOFs has been further measured to be approximately 3.01 eV.
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