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Updated: Jan 19, 2026

Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Templating conformations with cucurbiturils
Nathan A Thompson1, Héctor Barbero1, Eric Masson1
1Department of Chemistry and Biochemistry, Ohio University, Athens, Ohio 45701, USA. masson@ohio.edu.
Abstract:
The trans- and cis conformations of 5,5'-substituted 2,2'-dithiophenes can be stabilized when those are secured with two Cucurbit[8]uril macrocycles (CB[8]) on top of rigid 2,6- and 2,7-substituted naphthalenes, which respectively mimic the trans and cis conformations of the dithiophene. The substituents are Pt(ii) terpyridyl groups bearing CB[8]-binding sites at their 4'-position, as those form dimers in the presence of the macrocycle through Pt-Pt and dispersive interactions between the terpyridyl ligands.
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