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Updated: Dec 23, 2025
The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
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1,2-Diaza-4-phospholide complexes of chromium(ii): dipotassium organochromates behaving as single-molecule magnets
Jing Su1, Lei Yin, Zhongwen Ouyang
1Key Laboratory of Magnetic Molecules and Magnetic Information Materials, Ministry of Education, Shanxi Normal University, Gongyuan Street 1, Linfen, Shanxi Province 041004, China. wjzheng_sxnu@qq.com.
Abstract:
The 1,2-diaza-4-phospholide (dp-) dipotassium ate complexes of chromium(ii) {[(η1-N-3,5-tBu2dp)4Cr][(η5-(N,N,C,C,P))2-K(η1-O-THF)2]2} (5) and {[(η1-N-3,5-Ph2dp)4Cr][(η5-(N,N,C,C,P))2-K(η1-O-THF)2]2}∞ (6) were synthesized and characterized by X-ray single crystal structure analysis. Complex 5 with a near-square planar geometry at the chromium(ii) ion was unambiguously characterized by the high field electron paramagnetic resonance (HF-EPR) technique and magnetic measurements, revealing that it is a field-induced single-molecule magnet (SMM).
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