Surface structure-dependent photocatalytic O₂ activation for pollutant removal with bismuth oxyhalides

The purification of water and air by semiconductor photocatalysis is a rapidly growing area for academic research and industrial innovation, featured with ambient removal of organic or inorganic pollutants by using solar light as the energy source and atmospheric O₂ as the green oxidant. Both charge transfer and energy transfer from excited photocatalysts can overcome the spin-forbidden nature of O₂. Layered bismuth oxyhalides are a new group of two-dimensional photocatalysts with an appealing geometric and surface structure that allows the dynamic and selective tuning of O₂ activation at the surface molecular level. In this Feature Article, we specifically summarize our recent progress in selective O₂ activation by engineering surface structures of bismuth oxyhalides. Then, we demonstrate selective photocatalytic O₂ activation of bismuth oxyhalides for environmental control, including water decontamination, volatile organic compound oxidation and nitrogen oxide removal, as well as selective catalytic oxidations. Challenges and opportunities regarding the design of photocatalysts with satisfactory performance for potential environmental control applications are also presented.