Controlled decomposition of SF6 by electrochemical reduction
Sébastien Bouvet1, Bruce Pégot1, Stéphane Sengmany2
1Université Paris-Saclay, UVSQ, CNRS, UMR 8180, Institut Lavoisier de Versailles, 78035 Versailles Cedex, France.
Abstract:
The electroreduction of SF6 is shown at ambient temperature in acetonitrile using an array of platinum microelectrodes to improve the electrical detection. Its half reduction potential occurs at -2.17 V vs Fc+/Fc. The exact number of electrons for the full consumption of sulfur hexafluoride was determined and this gas further quantitatively transformed into environmentally benign fluoride anion and sulfur by electrochemical reduction.
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