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A versatile sea anemone-inspired strategy toward 2D hybrid porous carbons from functional molecular brushes

Xidong Lin1, Zelin Wang1, Ruliang Liu1

  • 1PCFM Lab and GDHPRC Lab, School of Chemistry, Sun Yat-Sen University, Guangzhou 510275, P. R. China. liushh27@mail.sysu.edu.cn wudc@mail.sysu.edu.cn.

Chemical Communications (Cambridge, England)
|January 14, 2021
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Aromatic Hydrocarbon Anions: Structural Overview01:18

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Neutral hydrocarbons like cyclopentadiene with an odd number of carbon atoms and one intervening CH2 group in the ring are not aromatic. Cyclopentadiene with 4 π electrons does not satisfy the 4n + 2 π electron rule. Additionally, the intervening CH2 group is sp3 hybridized and lacks a vacant p orbital, thereby interrupting the overlap of p orbitals in a continuous manner and preventing the delocalization of π electrons throughout the ring.
Due to the absence of continuous overlap of p...