Evaluation of Different Models for Non-Destructive Detection of Tomato Pesticide Residues Based on Near-Infrared...

In this study, the possibility of non-destructive detection of tomato pesticide residues was investigated using Vis/NIRS and prediction models such as PLSR and ANN. First, Vis/NIR spectral data from 180 samples of non-pesticide tomatoes (used as a control treatment) and samples impregnated with pesticide with a concentration of 2 L per 1000 L between 350-1100 nm were recorded by a spectroradiometer. Then, they were divided into two parts: Calibration data (70%) and prediction data (30%). Next, the prediction performance of PLSR and ANN models after processing was compared with 10 spectral preprocessing methods. Spectral data obtained from spectroscopy were used as input and pesticide values obtained by gas chromatography method were used as output data. Data dimension reduction methods (principal component analysis (PCA), Random frog (RF), and Successive prediction algorithm (SPA)) were used to select the number of main variables. According to the values obtained for root-mean-square error (RMSE) and correlation coefficient (R) of the calibration and prediction data, it was found that the combined model SPA-ANN has the best performance (RC = 0.988, RP = 0.982, RMSEC = 0.141, RMSEP = 0.166). The investigational consequences obtained can be a reference for the development of internal content of agricultural products, based on NIR spectroscopy.