Ozone-Activated Cataluminescence Sensor System for Dichloroalkanes Based on Silica Nanospheres

The detection and monitoring of dichloroalkanes, which are typical chlorinated volatile organic compounds (CVOCs) with obvious biological toxicity, is of significance for environmental pollution and public health. Herein, a novel ozone-activated cataluminescence (CTL) sensor system based on silica nanospheres was developed for highly sensitive and fast quantification of dichloroalkanes. A typical CTL system coupled with a plasma-ozone-assist unit was designed for promoting the CTL response of dichloroalkanes. The ozone generated by plasma provides a new pathway of catalytic oxidation process, which accompanied by the CTL signal amplification of dichloroalkanes results in an enhanced CTL sensor system with improved limit of detection (1,2-dichloroethane: 0.04 μg mL^-1, 1,2-dichloropropane: 0.03 μg mL^-1) and benign selective performance under the interference of CO₂, H₂O, NO, NO₂, SO₂, CS₂, and other common CVOCs. Moreover, a segmented CTL mechanism including co-adsorption of ozone and dichloroalkanes, thermal elimination, the ozonation route, and a luminous step was ratiocinated based on multiple characterizations and discussion. The proposed methodology and theory open up an attractive perspective for the analysis of less active volatile organic compounds.