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Updated: Oct 17, 2025

Hydrogen Production and Utilization in a Membrane Reactor
Published on: March 10, 2023
Electrochemical hydrogen formation catalysed by a Pd8 string
Tomoaki Tanase1, Kanako Nakamae1, Haruka Miyano1
1Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-nishi-machi, Nara 630-8506, Japan. tanase@cc.nara-wu.ac.jp.
Abstract:
The linear Pd8 complex supported by tetraphosphines reacted with HBF4 to give an unprecedented linear tetrapalladium complex with a terminal hydride, which promoted electrocatalytic hydrogen formation from HBF4 in acetonitrile. The 1D coordination polymer of Pd8 chain confined within Nafion film was applied to the electrocatalytic H2 formation.
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